PowerCLI: Get-LunPathState
Careful preparation is a key element to success. If you restart a storage controller, or even the whole storage, you should be very sure that all ESXi hosts have enough paths to every datstore. Sure, you can use the VMware vSphere C# client or the Web Client to check every host and every datastore. But if you have a large cluster with a dozen datastores and some Raw Device Mappings (RDMs), this can take a looooong time.